The TCR6 is a Thermocouple type sensor and behaves according to the Seebeck effect which describes the production of a charge shift on a conductor when there is a temperature difference along it.
The magnitude of the charge shift depends on the material and its electric properties.
If there is a conductive connection between two conductors made of different materials on one side and a temperature difference exists there, voltage is applied at the open ends.
This voltage depends on the temperature difference and the electric properties of both materials; since they and their characteristics are known, the temperature can be measured via the voltage.
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